کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1243167 | 1495839 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Critical approach to flow injection gradient titration as a calibration method
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
An attempt was made to demonstrate that flow injection gradient titration should not be considered as classical titration but rather as the indirect calibration method. This was shown experimentally by exploiting indirect spectrophotometric determination of chlorite ions in the presence of iron(II) in an acid environment with measurement of absorbance for the coloured Fe(II)/o-phenanthroline complex at 512Â nm. In such an analytical system, the peaks of a cut-off profile were obtained with two characteristic points corresponding to equivalent amounts of analyte and reagent, and peak widths were used as the analytical signal. The only difference between the approach presented and the classical flow injection titration procedure was not fundamental but of a technical nature and consisted in the fact that a sample loop of relatively great volume instead of a mixing chamber was installed into the flow injection system. The analytical performance of the developed calibration procedure is also presented and discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 96, 15 July 2012, Pages 34-38
Journal: Talanta - Volume 96, 15 July 2012, Pages 34-38
نویسندگان
Marcin Wieczorek, Joanna Kozak, PaweÅ KoÅcielniak, PaweÅ Knihnicki, Ewelina Pieprzyca,