کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1244248 969683 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Analysis of polycyclic aromatic hydrocarbons in solid matrixes by solid-phase microextraction coupled to a direct extraction device
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Analysis of polycyclic aromatic hydrocarbons in solid matrixes by solid-phase microextraction coupled to a direct extraction device
چکیده انگلیسی

Analysis of polycyclic aromatic hydrocarbons (PAHs) standards in model systems was carried out by solid-phase microextraction (SPME) coupled to a direct extraction device (DED) and subsequent gas chromatography/mass spectrometry (GC/MS). PAHs standard was added to gelatine systems at different concentrations. Extraction process was carried out by SPME-DED at 25 °C for 60 min. Polydimethylsiloxane 100 μm (PDMS 100 μm), divinylbenzene/polydimethylsiloxane 65 μm (DVB/PDMS 65 μm) and polyacrilate 85 μm (PA 85 μm) SPME fibres were tested. SPME-DED satisfactorily extracted PAHs with a molecular weight (MW) lower than 206 from the gelatine system. All fibres showed a good reproducibility (residual standard deviation (RSD) between 5.24% and 18.25%), linearity (regression coefficients between 0.8959 and 0.9983) and limit of detection (LOD) (between 0.008 and 0.138 ng mL−1). Presence of PAHs in different smoked meat products was also tested by SPME-DED. Different low MW PAHs were satisfactorily detected from all the foodstuffs studied. SPME-DED appears as a rapid, non-destructive technique for primary screening of low MW PAHs in solid matrixes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 71, Issue 2, 15 February 2007, Pages 751–757
نویسندگان
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