کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1246476 | 969756 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Probing trace Pb2+ using electrodeposited N,Nâ²-(o-phenylene)-bis-benzenesulfonamide polymer as a novel selective ion capturing film
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel film modified electrode for the determination of trace lead was developed in this work. The modified electrode was prepared by the electropolymerization of N,Nâ²-(o-phenylene)-bis-benzenesulfonamide (PBSA) as the ion capturing reagent to create the functional film. The modified electrode shows a high selectivity towards Pb2+ over interfering cations, e.g. Cu2+, Cd2+, Co2+, Ni2+, Zn2+, Cr2+, and the calibration curve was linear in the concentration range of 2.0Â ÃÂ 10â9 to 1.0Â ÃÂ 10â7Â M with correlation coefficient of 0.999. For 20Â min accumulation, detection limit of 1.0Â ÃÂ 10â9Â M was obtained at the signal to noise ratio of 3. Analytical availability of the modified electrode was demonstrated by the application for samples from pond water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 70, Issue 2, 15 September 2006, Pages 432-436
Journal: Talanta - Volume 70, Issue 2, 15 September 2006, Pages 432-436
نویسندگان
Lei Zhang, Wei Li, Mianhong Shi, Jilie Kong,