کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1246501 | 969758 | 2010 | 6 صفحه PDF | دانلود رایگان |
Pt/polypyrrole (PPy) hybrid hollow microspheres were successfully prepared by wet chemical method via Fe3O4 template and evaluated as electrocatalysts for the reduction of hydrogen peroxide. The as-synthesized products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), X-ray diffraction (XRD), inductive coupled plasma emission spectrum (ICP) and Fourier-transform infrared spectra (FTIR) measurements. The results exhibited that ultra-high-density Pt nanoparticles (NPs) were well deposited on the PPy shell with the mean diameters of around 4.1 nm. Cyclic voltammetry (CV) results demonstrated that Pt/PPy hybrid hollow microspheres, as enzyme-less catalysts, exhibited good electrocatalytic activity towards the reduction of hydrogen peroxide in 0.1 M phosphate buffer solution (pH = 7.0). The composite had a fast response of less than 2 s with linear range of 1.0–8.0 mM and a relatively low detection limit of 1.2 μM (S/N = 3). The sensitivity of the sensor for H2O2 was 80.4 mA M−1 cm−2.
Journal: Talanta - Volume 81, Issue 3, 15 May 2010, Pages 813–818