کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1250299 | 1495983 | 2015 | 16 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: X-ray diffraction, spectroscopic (IR, Raman) and DSC studies of bis(betainium) p-toluenesulfonate monohydrate crystal X-ray diffraction, spectroscopic (IR, Raman) and DSC studies of bis(betainium) p-toluenesulfonate monohydrate crystal](/preview/png/1250299.png)
• The BBTSH crystal undergoes dehydration at 349 K.
• Studied crystal shows the cold crystallization phenomenon.
• The existence of short and strong H-bond was detected.
• Despite dehydration the betaine dimer is not destroyed.
• BBTSH was characterized by XRD and IR in the wide temperature range.
Bis(betainium) p-toluenesulfonate monohydrate (abbreviated as BBTSH) was studied at various temperatures by X-ray diffraction, differential scanning calorimetry and vibrational spectroscopy methods. DSC curves of BBTSH show a peak at about 349 K which corresponds to water escape from the crystal, and reveal the “cold crystallization” phenomenon. BBTSH crystallizes in the P21/c space group of monoclinic system. After heating above 349 K the compound dehydrates, the crystal system changes to triclinic, the monocrystalline samples become non-merohedral twins. The BBTSH crystal comprises p-toluenesulfonic anions, monoprotonated betaine dimers and water molecules. Three kinds of hydrogen bonds are present in the crystal: strong, asymmetric and almost linear OH⋯O hydrogen bond (R(O⋯O) = 2.463(2) Å), weak OwH⋯O hydrogen bonds (R(Ow⋯O) = 2.820(2) − 2.822(2) Å) and weak CH⋯O hydrogen bonds (R(C⋯O) = 3.295(2) − 3.416(2) Å). The νaOHO vibration of the strongest hydrogen bond in the crystal gives rise to an intense broad absorption with numbers of transmission windows in the low wavenumber region of the infrared spectra. Coupling between νCO stretching vibrations of two COO groups of the betaine dimer was detected. The process corresponding to the loss of water is accompanied by the breakage of strong OH⋯O hydrogen bonds in betaine dimers and rearrangement inside half of the betaine dimers. This rearrangement results in formation of the new betaine dimers with OH∙∙∙O hydrogen bond of similar strength as corresponding bond in the hydrated form (BBTSH).
Journal: Vibrational Spectroscopy - Volume 76, January 2015, Pages 6–21