کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1250300 1495983 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Near-infrared study of the interaction of pyridine with acid-treated montmorillonite
ترجمه فارسی عنوان
مطالعه نزدیک مادون قرمز در تعامل پیریدین با مونتموریلونیت درمان شده با اسید
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی

The effect of acid treatment of montmorillonite on the creation of acid sites was investigated by near infrared (NIR) spectroscopy using pyridine as a probe molecule. Na-form of SAz-1 montmorillonite was treated in HCl for 2–8 h. Gradual decrease of the intensities of the bands related to structural OH groups reflected the release of the octahedral atoms from Na-SAz upon protons attack. A new band near 7315 cm−1 due to SiOH overtone confirmed the formation of protonated silica. After exposure of the Na-SAz to pyridine vapors the intensity of the (ν+δ)H2O(ν+δ)H2O band diminished indicating the partial replacement of water molecules by pyridine. Disappearance of the SiOH band in the spectra of acid-treated samples revealed that silanol groups as weak Brønsted acid sites formed H-bonds with pyridine-nitrogen. After pyridine adsorption, its CH overtone band (2νCH) appeared near 6000 cm−1. For examining the strength of the pyridine bonding, samples were heated up to 230 °C. The re-appearance of the 7315 cm−1 band and decreased intensity of the 2νCH overtone confirmed the release of the H-bonded pyridine molecules. Almost complete loss of pyridine band was observed for Na-SAz-py and for the 8 h treated sample heated above 170 °C, while a well-resolved 2νCH band, but shifted to higher wavenumbers, was still present in the spectra of the samples dissolved in HCl for 2 and 4 h. Partly leached acid-montmorillonite provided protons for generation of pyridinium cations. The bands at 6096 and 6065 cm−1 observed in the spectra of SAz-2 h-py and SAz-4 h-py heated at 230 °C were assigned to the C–H vibrations of pyridinium cations. The results showed that NIR spectroscopy can distinguish between different pyridine species on montmorillonite surface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 76, January 2015, Pages 22–30
نویسندگان
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