کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1251894 | 1495994 | 2013 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Temperature-dependent Raman spectroscopy studies of phase transformations in the K2WO4 and the MgMoO4 crystals Temperature-dependent Raman spectroscopy studies of phase transformations in the K2WO4 and the MgMoO4 crystals](/preview/png/1251894.png)
Temperature-dependent Raman spectroscopy studies of K2WO4 and MgMoO4 polycrystals were performed in order to obtain information about vibrational and structural changes in these materials as a function of temperature. The stability of the monoclinic phase for both K2WO4 and MgMoO4 samples was assessed and our results indicated that this phase is stable in the 295–723 K and 300–770 K ranges for K2WO4 and MgMoO4, respectively. It was observed that both samples underwent two phase transformations above room temperature. The first phase transformations which occur at about 633 K and 640 K for K2WO4 and MgMoO4, respectively, is most likely connected with weak tilting and/or rotations of WO4/MoO4 tetrahedral units that lead to a disorder in the oxygen sublattice. Raman spectroscopy data also indicated that K2WO4 and MgMoO4 exhibited a first-order phase transition at around 723 K and 770 K, respectively, changing from monoclinic to hexagonal symmetry.
Journal: Vibrational Spectroscopy - Volume 65, March 2013, Pages 58–65