کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1272164 | 1497479 | 2014 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The effect of microstructure on the hydrogenation of Mg/Fe thin film multilayers The effect of microstructure on the hydrogenation of Mg/Fe thin film multilayers](/preview/png/1272164.png)
• In an attempt to destabilize MgH2, thin layers of Mg were sandwiched between Fe.
• Nanoconfined MgH2 is indeed destabilized when interfaced with Fe.
• This requires control over the microstructure of the as-deposited Mg.
Nanoconfined magnesium hydride can be simultaneously protected and thermodynamically destabilized when interfaced with materials such as Ti and Fe. We study the hydrogenation of thin layers of Mg (<14 nm) nanoconfined in one dimension within thin film Fe/Mg/Fe/Pd multilayers by the optical technique Hydrogenography. The hydrogenation of nanosized magnesium layers in Fe/Mg/Fe multilayers surprisingly shows the presence of multiple plateau pressures, whose nature is thickness dependent. In contrast, hydrogen desorption occurs via a single plateau which does not depend on the Mg layer thickness. From structural and morphological analyses with X-ray diffraction/reflectometry and cross-section TEM, we find that the Mg layer roughness is large when deposited on Fe and furthermore contains high-angle grain boundaries (GB's). When grown on Ti, the Mg layer roughness is low and no high-angle GB's are detected. From a Ti/Mg/Fe multilayer, in which the Mg layer is flat and has little or no GB's, we conclude that MgH2 is indeed destabilized by the interface with Fe. In this case, both the ab- and desorption plateau pressures are increased by a factor two compared to the hydrogenation of Mg within Ti/Mg/Ti multilayers. We hypothesize that the GB's in the Fe/Mg/Fe multilayer act as diffusion pathways for Pd, which is known to greatly alter the hydrogenation behavior of Mg when the two materials share an interface.
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 30, 13 October 2014, Pages 17092–17103