کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1273630 | 1497526 | 2013 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Photoelectrochemical application of mesoporous TiO2/WO3 nanohoneycomb prepared by sol–gel method Photoelectrochemical application of mesoporous TiO2/WO3 nanohoneycomb prepared by sol–gel method](/preview/png/1273630.png)
• Mesoporous TiO2/WO3 nanohoneycomb was prepared by sol–gel method.
• Optical absorption of TiO2/WO3 revealed a red shift and smaller band gap energy.
• It showed a better photoelectrochemical efficiency of water splitting.
• TiO2/WO3 has higher reactive surface area and better separation efficiency.
A mesoporous TiO2/WO3 nanohoneycomb at a molar ratio of 3:1 was prepared by sol–gel method for photoelectrochemical splitting of water. In order to create a highly porous structure, the composite TiO2/WO3 with a block copolymer internal template was deposited on the substrate covered with polystyrene (PS) nanospheres. A mesoporous TiO2/WO3 composite nanohoneycomb was obtained after removing the PS spheres and copolymer by thermal treatment. It exhibited a lower band gap energy than TiO2 so that the optical absorption edge was shifted toward the visible light region. It also showed a better photoelectrochemical efficiency of water splitting and higher production of hydrogen due to lower energy gap, higher reactive surface area, and better charge separation efficiency.
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 19, 27 June 2013, Pages 7750–7755