Synthesis, structural characterization, and hydrolysis of Ammonia Borane (NH3BH3) as a hydrogen storage carrier

• NH3BH3 was prepared by one-pot chemical.
• NH3BH3 was successfully synthesized with 98% purity.
• The maximum hydrogen generation rate was observed as 5474.80 ml min−1 g cat−1.
• The max. synthesis yield was 92.18% for 40 °C and 120 min.

In the present study, synthesis, structural characterization, and hydrolysis of the promising hydrogen storage carrier ammonia borane (NH3BH3), were investigated. NH3BH3 was prepared by one-pot chemical reaction between sodium borohydride (NaBH4) and different ammonia salts [NH4X, X: SO4, CO3, Cl] in the presence of solvent, tetrahydrofurane (THF). Synthesizes with different temperatures (20–40 °C), reaction times (30–130 min), amount of added THF volume (50–200 ml) and NaBH4/(NH4)2SO4 input molar ratios (0.47–0.75) were performed in order to find the optimum reaction conditions for obtaining maximum product yield. The characterization of NH3BH3 products was carried out by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy (RS), elemental analysis (C, H, N, O) and NMR spectroscopy. Characterization results indicated that NH3BH3 as a crystalline powder at 98% purity was achieved with 92.18% production yield. Additionally, hydrolysis of product NH3BH3 in the presence of amorphous Co–B catalyst at 22–80 °C under magnetic stirring (700 rpm) was performed. The maximum hydrogen generation rate was 5447.80 ml min−1 g cat−1 and the hydrolysis reaction kinetics were clarified based on zero-order, first-order and Langmuir–Hinshelwood kinetic models.

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