One-step synthesis of Cu@FeNi core–shell nanoparticles: Highly active catalyst for hydrolytic dehydrogenation of ammonia borane

This paper investigates a facile and one-step synthesis of trimetallic magnetic Cu@FeNi core–shell nanoparticles, which are composed of crystalline Cu cores and amorphous FeNi shells, at room temperature under ambient atmosphere within 2 min. It is found that among the Cu@FeNi system, Cu0.4@Fe0.1Ni0.5 shows the best synergistic performance for catalyzing the hydrolytic dehydrogenation of ammonia borane with the activation energy of 32.9 kJ/mol, being lower than most of the reported data, and the catalytic activity of Cu0.4@Fe0.1Ni0.5 is much better than its monometallic, bimetallic and trimetallic counterparts whether in states of pure metals, alloys or physical mixtures. Further, the present catalyst has a good recycle stability with an easy magnetic separation method.

► Cu0.4@Fe0.1Ni0.5 core–shell nanoparticles have been synthesized within 2 min.
► Cu0.4@Fe0.1Ni0.5 has good catalytic activity/stability to hydrogen generation.
► This work has innovation for catalyst synthesis and its application on energy.