کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1275346 | 1497559 | 2012 | 8 صفحه PDF | دانلود رایگان |
This paper presented non-kinetic losses in PEM fuel cells under an accelerated stress test of catalyst support. A cathode with carbon-supported Pt catalyst was prepared and characterized during potential hold at 1.2 V vs. SHE in a PEM fuel cell. Irreversible losses caused by carbon corrosion were evaluated using a variety of electrochemical characterizations including cyclic voltammetry, linear sweep voltammetry, electrochemical impedance spectroscopy, and polarization technique. Ohmic losses at the cathode during potential hold were determined using its capacitive responses. Concentration losses in the PEM fuel cell were analyzed in terms of Tafel behavior and thin film/flooded-agglomerate dynamics.
► Polarization losses caused by carbon corrosion in PEM fuel cells were investigated.
► Ionic resistances in membrane and catalyst layer (CL) with time were measured.
► Concentration losses in CL and non-CL with time were quantified.
► Concentration losses were explained by thin film/flooded-agglomerate dynamics.
Journal: International Journal of Hydrogen Energy - Volume 37, Issue 10, May 2012, Pages 8451–8458