Oxidation behavior of (Co,Mn)3O4 coatings on preoxidized stainless steel for solid oxide fuel cell interconnects

Ceramic coatings are being explored to extend the lifetime of stainless steel interconnects in planar Solid Oxide Fuel Cells (SOFCs). One promising coating is Co1.5Mn1.5O4 spinel, which is deposited using various techniques, resulting in different coating thicknesses, compositions and microstructures. In this study, stainless steel 441HP samples were subjected to three levels of preoxidation (0, 3, 10 and 100 h in 800 °C lab air) prior to coating. Samples were coated with 2 μm CoMn alloy using magnetron sputtering and were subsequently annealed in 800 °C air for 0, 10, 100 or 1650 h. Oxidation behaviors were evaluated as a function of these exposures, as well as in dual atmospheres and during area specific resistance (ASR) measurements in 800 °C lab air. Preoxidation was found to inhibit Fe and Cr transport from the stainless steel into the coating and preoxidized samples exhibited a substantially thinner surface layer after oxidation. After ASR testing for 1650 h in 800 °C air, the trend of the preoxidized sample values remained level while trend of the non-preoxidized sample values showed an increase. Observed oxidation behaviors, their possible mechanisms, and implications for SOFC interconnects are presented and discussed.

► Preoxidation reduces Fe and Cr transport into (Co,Mn)3O4 coating.
► Preoxidation reduces growth of surface oxide layer in oxidizing conditions.
► Oxide deposited coatings reduce Fe transport into coating in oxidizing conditions.