کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1277751 | 1497592 | 2011 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Performance of a sulfur-resistant commercial WGS catalyst employing industrial coal-derived syngas feed
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Performance of a sulfur-resistant commercial WGS catalyst employing industrial coal-derived syngas feed Performance of a sulfur-resistant commercial WGS catalyst employing industrial coal-derived syngas feed](/preview/png/1277751.png)
چکیده انگلیسی
Catalyst pretreatment and reaction conditions (reaction temperature, H2O/CO molar ratio and space velocity) for the Water Gas Shift reaction were studied in a bench scale set-up, using a commercial catalyst and an industrial coal-derived syngas feed. Catalytic activity showed an important dependence on reaction temperature and space velocity although it remained almost constant with varying H2O/CO molar ratio. The effect of reduction with H2 or sulfide activation with H2S or carbonyl sulfide (COS) was also studied, giving good catalytic results for 94 ppm S provided by either H2S or COS as sulfide agents. Selectivity to hydrogen was close to 100% in all catalytic reaction tests.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 1, January 2011, Pages 44–51
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 1, January 2011, Pages 44–51
نویسندگان
A.R. de la Osa, A. De Lucas, J.L. Valverde, A. Romero, I. Monteagudo, P. Sánchez,