کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1277965 | 1497602 | 2010 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Single-step fabrication of ABPBI-based GDE and study of its MEA characteristics for high-temperature PEM fuel cells Single-step fabrication of ABPBI-based GDE and study of its MEA characteristics for high-temperature PEM fuel cells](/preview/png/1277965.png)
Single-step fabrication of a Poly(2,5-benzimidazole) (ABPBI)-based gas diffusion electrode (GDE) by directly adding a carbon-supported-catalyst to a homogeneous ABPBI solution prior to deposition and its membrane electrode assembly (MEA) were investigated for high-temperature proton exchange membrane (PEM) fuel cell applications. The ABPBI and LiCl dosages of the catalyst layer were varied. The characterizations of the resulting electrodes and/or MEA for the gas permeability, electrical resistance, specific electrochemical surface area, AC impedance, cyclic voltammetry and high-temperature PEM fuel cell performance were carried out. The high-temperature PEM fuel cell was successfully demonstrated at temperatures of up to 180 °C under ambient pressure operation. The fuel cell performance was evaluated by using dry hydrogen/oxygen gases, which added the advantage of eliminating the complicated humidification system of Nafion cells. The obtained results revealed that a catalyst layer with an ABPBI content of 15 wt.% and an ABPBI/LiCl ratio of 1:2 was sufficient to obtain the optimal cell performance with better electrochemical properties of low cell impedance, high electrochemical activity, low contact resistance and short activation time.
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 15, August 2010, Pages 7866–7873