کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1278055 | 1497641 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts Kinetics of reduction of water to hydrogen by visible light on alumina supported Pt–CdS photocatalysts](/preview/png/1278055.png)
چکیده انگلیسی
The kinetics of hydrogen production from photolysis of water on alumina supported Pt–CdS catalyst using visible light has been studied. An induction period with negligible rate was observed upon illumination of catalyst. The rate gradually increases and again falls down. The rate has been observed to be proportional to the sulfide ions adsorbed on the surface of CdS. The induction period has been related to the re-establishment of adsorption equilibrium of sulfide ions on the catalyst surface under illumination. The decrease in rate is due to the deactivation of catalyst by hydrogen. A power law type rate expression for hydrogen production has been proposed which takes into account the deactivation of the catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 1, January 2009, Pages 130–137
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 1, January 2009, Pages 130–137
نویسندگان
Namita Sahu, S.N. Upadhyay, A.S.K. Sinha,