Performance evaluation of a fuel processing system based on membrane reactors technology integrated with a PEMFC stack

The development of fuel cells is promised to enable the distributed generation of electricity in the near future. However, the infrastructure for production and distribution of hydrogen, the fuel of choice for fuel cells, is currently lacking. Efficient production of hydrogen from fuels that have existing infrastructure (e.g., natural gas, gasoline or LPG) would remove a major drawback to use fuel cells for distributed power generation.The aim of this paper is to define the better operating conditions of an innovative hydrogen generation system (the fuel processing system, FP) based on LPG steam reforming, equipped with a membrane shift reactor, and integrated with a PEMFC (Proton Exchange Membrane Fuel Cell) stack of 5 kWel.With respect to the conventional hydrogen generation systems, the use of membrane reactors (MRs) technology allows to increase the hydrogen generation and to simplify the FP-PEMFC plant, because the CO removal system, needed to reduce the CO content at levels required by the PEMFC, is avoided.Therefore, in order to identify the optimal operating conditions of the FP-PEMFC system, a sensitivity analysis on the fuel processing system has been carried out by varying the main operating parameters of both the reforming reactor and the membrane water gas shift reactor. The sensitivity analysis has been performed by means of a thermochemical model properly developed.Results show that the thermal efficiency of the fuel processing system is maximize (82.4%, referred to the HHV of fuels) at a reforming temperature of 800 °C, a reforming pressure of 8 bar, and an S/C molar ratio equal to 6. In the nominal operating condition of the PEMFC stack, the FP-PEMFC system efficiency is 36.1% (39.0% respect to the LHV).

► We model an LPG reforming system equipped with a membrane shift reactor.
► The hydrogen production depends on reforming pressure, temperature and S/C ratio.
► In the optimal operating conditions the thermal efficiency is equal to 82.4% (HHV).
► The LPG reforming system has been integrated with a PEMFC.
► The overall efficiency of the integrated system is 36.1% (HHV).