کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1279153 | 1645388 | 2011 | 7 صفحه PDF | دانلود رایگان |
In this work, we prepared platinum doped on activated carbons/metal-organic frameworks-5 hybrid composites (Pt-ACs-MOF-5) to obtain a high hydrogen storage capacity. The surface functional groups and surface charges were confirmed by Fourier transfer infrared spectroscopy (FT-IR) and zeta-potential measurement, respectively. The microstructures were characterized by X-ray diffraction (XRD). The sizes and morphological structures were also evaluated using a scanning electron microscopy (SEM). The pore structure and specific surface area were analyzed by N2/77 K adsorption/desorption isotherms. The hydrogen storage capacity was studied by BEL-HP at 298 K and 100 bar. The results revealed that the hydrogen storage capacity of the Pt-ACs-MOF-5 was 2.3 wt.% at 298 K and 100 bar, which is remarkably enhanced by a factor of above five times and above three times compared with raw ACs and MOF-5, respectively. In conclusion, it was confirmed that Pt particles played a major role in improving the hydrogen storage capacity; MOF-5 would be a significantly encouraging material for a hydrogen storage medium as a receptor.
► Pt nanoparticles play an important role in hydrogen storage characteristics due to the hydrogen spill over effect.
► Pt loaded activated carbons (Pt-ACs) play a role as an efficient primary spillover receptor.
► Pt-ACs-MOF-5 hybrid composites that are characterized by charge-induced dipole interactions, and it is possible to enhance the hydrogen storage capacity as a secondary receptor.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 14, July 2011, Pages 8381–8387