کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1279316 | 1497580 | 2011 | 10 صفحه PDF | دانلود رایگان |
IrO2 electrocatalysts were prepared and electrochemically characterized for the oxygen evolution reaction in a Solid Polymer Electrolyte (SPE) electrolyzer. By using a sulfite complex-based preparation procedure, an amorphous iridium oxide precursor was obtained at 80 °C, which was, successively, calcined at different temperatures: 350 °C, 400 °C and 450 °C. A physico-chemical characterization was carried out by X Ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and X-ray-photoelectron spectroscopy (XPS). The various IrO2 catalysts were sprayed onto a Nafion 115 membrane with a loading of 2.5 mg cm−2 to form the anode. A Pt/C catalyst (Pt loading 0.5 mg cm−2) was used as cathode. The best electrochemical performance was obtained for the cell based on the IrO2 calcined at 350 °C. The maximum current density at high potentials (1.8 V) was about 1.75 A cm−2. Accelerated time-tests at 2 A cm−2 demonstrated a suitable stability of the IrO2 calcined at 350 °C; however, the intrinsic stability appeared to increase with the calcination temperature. The sample calcined at 400 °C could represent a good compromise between performance and intrinsic stability.
► A sulfite complex-based preparation procedure was used to prepare IrO2 catalysts.
► IrO2 catalysts were investigated for the oxygen evolution reaction in SPE electrolyzers in terms of performance and stability.
► The IrO2 sample calcined at 400 °C could represent a good compromise between performance and intrinsic stability.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 13, July 2011, Pages 7822–7831