کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1279546 | 1497583 | 2011 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Nanosized Ce0.8Sm0.2O1.9 infiltrated GdBaCo2O5+δ cathodes for intermediate-temperature solid oxide fuel cells Nanosized Ce0.8Sm0.2O1.9 infiltrated GdBaCo2O5+δ cathodes for intermediate-temperature solid oxide fuel cells](/preview/png/1279546.png)
In this paper, Ce0.8Sm0.2O1.9 (SDC) nanoparticles modified GdBaCo2O5+δ (GBCO) cathodes were fabricated by an infiltration technique and evaluated for intermediate-temperature solid oxide fuel cells (IT-SOFCs). Good chemical compatibility between GBCO and infiltrated SDC was confirmed by X-ray diffraction (XRD) characterization. SDC nanoparticles (∼40 nm) formed continuous ionic-conducting phase on porous GBCO backbone, which contributed to significantly improved electro-catalytic property. At 600 °C, the composite cathode with 3.3 mg cm−2 SDC loading exhibited encouragingly low Rp value of 0.1 Ω cm2, which was much lower than 0.43 Ω cm2 of pure-GBCO cathode. As revealed by PO2 dependence of impedance spectra, the oxygen reduction reaction was mainly limited by charge-transfer processes. Furthermore, a stable operation of 80 h was obtained at 600 °C. Our study implies that infiltrated GBCO cathode is very attractive for application in IT-SOFC cathode.
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 10, May 2011, Pages 6151–6159