کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1282095 | 1497693 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and hydrogenation properties of Mg-La-Ni-H system by reactive mechanical alloying
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We have synthesized Mg-30Â mass%LaNi2.28 composite material and investigated its hydrogenation behaviour. The reactive mechanical alloying process of the mixture of Mg and LaNi2.28 was studied. It is found that a composite of MgH2, La4H12.9 and Mg2NiH4 formed after 80Â h ball-milling under 3.0Â MPa hydrogen. Scanning electron microscopic analysis indicated that these new phases are distributed homogeneously. This composite shows excellent hydriding properties even at moderate temperature. Under 3.0Â MPa hydrogen pressure it absorbed more than 80% of its full capacity in the temperature range of 473-553Â K within less than 1Â min. The maximum hydrogen absorption capacity at 553Â K is 5.4Â mass%. The enhanced hydriding properties could be attributed to the fine and uniform particles and a synergeticly catalytic effect generated by mechanical milling.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 31, Issue 5, April 2006, Pages 581-585
Journal: International Journal of Hydrogen Energy - Volume 31, Issue 5, April 2006, Pages 581-585
نویسندگان
Fabing Li, Lijun Jiang, Jun Du, Shumao Wang, Xiaopeng Liu, Feng Zhan,