Improving hydrogen storage properties of magnesium based alloys by equal channel angular pressing

Equal channel angular pressing was applied to a commercial magnesium alloy ZK60 in order to improve its hydrogen storage properties. The microstructure refinement and increase in the density of crystal lattice defects caused by equal channel angular pressing increase hydrogen desorption pressure, change the slope of the pressure plateau in pressure-composition isotherms, decrease the pressure hysteresis, and accelerate the hydrogen desorption kinetics. It is argued that a proper design of the defect structure of materials is a key element in the search for economically viable and environmentally acceptable solutions for mobile hydrogen storage based on metal hydrides.