کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1283363 | 1497639 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural characteristics and hydrogen storage properties of Ca3.0âxMgxNi9 (x = 0.5, 1.0, 1.5 and 2.0) alloys
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The effect of Mg content on the structural characteristics and hydrogen storage properties of the Ca3.0âxMgxNi9 (x = 0.5, 1.0, 1.5 and 2.0) alloys was investigated. The lattice parameters and unit cell volume of the PuNi3-type (Ca, Mg)Ni3 main phase decreased with increasing Mg content. The 6c site of PuNi3-type structure was occupied by both Ca and Mg atoms. Moreover, the occupation factor of Ca on the 6c site decreased with the increase of Mg content. The hydrogen absorption capacity of the alloys decreased due to higher Mg content. However, the thermodynamic properties of hydrogen absorption and desorption were improved and the plateau pressures were increased. When x = 1.5-2.0, the Ca3.0âxMgxNi9 alloys had favorable enthalpy (ÎH) and entropy (ÎS) of hydride formation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 3, February 2009, Pages 1483-1488
Journal: International Journal of Hydrogen Energy - Volume 34, Issue 3, February 2009, Pages 1483-1488
نویسندگان
T.Z. Si, Q.A. Zhang, G. Pang, D.M. Liu, N. Liu,