کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1283398 | 1497903 | 2016 | 10 صفحه PDF | دانلود رایگان |
• Graphene wrapped LiMn0.5Fe0.5PO4 is synthesized using Li3PO4/graphene oxide.
• The mechanism and composite structure evolution are investigated.
• The LiMn0.5Fe0.5PO4 particles inherit the size of Li3PO4 nanoparticles.
• The composite delivers capacity 101.3 mA h g−1 at 10 C.
A novel strategy for confined synthesis of graphene wrapped nano-sized LiMn0.5Fe0.5PO4 hybrid composite has been developed, including co-precipitation and solvothermal reactions. The LiMn0.5Fe0.5PO4 nanoparticles with a constrained diameter of 20 nm are homogeneously wrapped by a continuous interconnected graphene sheets. The mechanism and composite structure evolution during the process are carefully investigated and discussed. With the shortened Li+ diffusion paths and enhanced electron conductivity, the hybrid composite shows high discharge capacity and superior rate performance with the discharge capacities of 166 mA h g−1 at 0.1 C and 90 mA h g−1 at 20 C. Excellent cycle stability is also demonstrated with only about 7.8% capacity decay after 500 cycles at 1 C.
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Journal: Journal of Power Sources - Volume 329, 15 October 2016, Pages 94–103