Hydrogen generation from liquid phase catalytic reforming of sugar solutions using metal-supported catalysts

Most of the hydrogen production processes are designed for large-scale industrial uses and are not suitable for a compact hydrogen device to be used in systems like solid polymer fuel cells. Integrating the reaction step, the gas purification and the heat supply can lead to small-scale hydrogen production systems. The aim of this research is to study the influence of several reaction parameters on hydrogen production using liquid phase reforming of sugar solution over Pt, Pd, and Ni supported on nanostructured supports. It was found that the desired catalytic pathway for H2H2 production involves cleavage of C–C, C–H and O–H bonds that adsorb on the catalyst surface. Thus a good catalyst for production of H2H2 by liquid-phase reforming must facilitate C–C bond cleavage and promote removal of adsorbed CO species by the water–gas shift reaction, but the catalyst must not facilitate C–O bond cleavage and hydrogenation of CO or CO2CO2. Apart from studying various catalysts, a commercial Pt/γγ-alumina catalyst was used to study the effect of temperature at three different temperatures of 458, 473 and 493 K. Some of the spent catalysts were characterised using TGA, SEM and XRD to study coke deposition. The amorphous and organised form of coke was found on the surface of the catalyst.