کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1284640 | 1498033 | 2012 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Enhanced high-current capacitive behavior of graphene/CoAl-layered double hydroxide composites as electrode material for supercapacitors Enhanced high-current capacitive behavior of graphene/CoAl-layered double hydroxide composites as electrode material for supercapacitors](/preview/png/1284640.png)
Graphene nanosheets (GNS)/CoAl-layered double hydroxide (CoAl-LDH) composite with a laminated structure is fabricated by a simple refluxing method. It is found that CoAl-LDH lamellar crystallites gradually self-assemble on the graphene oxide (GO) which is reduced to GNS during the refluxing procedure in the presence of urea. The GNS/CoAl-LDH composite has a higher specific surface area (23.4 m2 g−1) and superior electrochemical performance. As electrode material for supercapacitors, the composite shows a maximum specific capacitance of 711.5 F g−1 at low current density of 1 A g−1, and it remains 516.8 F g−1 when the current density increase to 10 A g−1. Furthermore, the capacitance keeps at least about 81% (compare with 64% for that of pure LDH) after 2000 cycles at 10 A g−1, indicating the composite has excellent high-current capacitive behavior.
CoAl-LDH crystallites grow on graphene sheets by refluxing process and they exhibit excellent high-rate performance and good cycling ability.Figure optionsDownload as PowerPoint slideHighlights
► Graphene sheets/CoAl-layered double hydroxide composites were synthesized in one pot.
► The composites show laminated structures without well-defined morphologies.
► The composites show superior electrochemical performance at a high current density.
► The composites could have practical applications for supercapacitors.
Journal: Journal of Power Sources - Volume 199, 1 February 2012, Pages 395–401