کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1285565 | 1497924 | 2016 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Highly efficient dye-sensitized solar cells achieved through using Pt-free Nb2O5/C composite counter electrode and iodide-free redox couples Highly efficient dye-sensitized solar cells achieved through using Pt-free Nb2O5/C composite counter electrode and iodide-free redox couples](/preview/png/1285565.png)
• We synthesized a composite of Nb2O5/C for dye-sensitized solar cells (DSCs).
• The catalytic activities of Nb2O5/C were enhanced remarkably as compared with Nb2O5.
• The improved catalytic activity of the composite can be attributed to the enhanced surface area and conductivity.
• The DSCs using Nb2O5/C counter electrode showed a high efficiency of 9.86%.
To improve the catalytic activity of Nb2O5, a composite Nb2O5/C (Nb2O5 imbedded in carbon support) is synthesized with a simple in situ method and then introduced the composite into dye-sensitized solar cells (DSCs) as a counter electrode (CE) catalyst. Based on the analysis of the cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel-polarization curve measurements, the catalytic activity of the Nb2O5/C composite for the regeneration of iodide-free redox couples of polysulfide (T2/T−) and cobalt complex (Co3+/2+) is indeed enhanced significantly as compared with pure Nb2O5, because the composite electrode eliminates the particle aggregation and forms a mesoporous network structure with large pore size. The T2/T− electrolyte based DSCs with Nb2O5/C CE yields a high power conversion efficiency (PCE) of 6.11%, generating a great improvement of 63.8% as compared to the Pt CE based DSCs. In addition, the Nb2O5/C exhibits higher catalytic activity than Pt for regenerating the Co3+/2+ redox couple and the DSCs using Nb2O5/C CE shows a high PCE of 9.86%.
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Journal: Journal of Power Sources - Volume 308, 15 March 2016, Pages 37–43