کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1294816 | 973638 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A simple route to high performance nanometric metallic materials for Li-ion batteries involving the use of cellulose: The case of Sb
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A facile method for obtaining nanometric Sb particles that perform well as electrode in lithium cells is proposed. The method involves reducing SbCl3 with NaBH4 in solution and in the presence of commercial cellulose fibers. Once dry, the resulting composite requires no additive for use in lithium cells, where it delivers high capacity values (ca. 470 mAh g−1) after the first few cycles. We believe that cellulose acts as a buffer alleviating the mechanical stress to which the element is subject during the lithium insertion/de-insertion process. In fact, an electrode made from nanometric Sb prepared in the absence of cellulose was found to perform poorly; thus the capacity delivered after the fifteenth cycle was below 100 mAh g−1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 175, Issue 1, 3 January 2008, Pages 553–557
Journal: Journal of Power Sources - Volume 175, Issue 1, 3 January 2008, Pages 553–557
نویسندگان
Álvaro Caballero, Julián Morales, Luis Sánchez,