کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1297071 1498393 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxygen separation from compressed air using a mixed conducting perovskite-type oxide membrane
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Oxygen separation from compressed air using a mixed conducting perovskite-type oxide membrane
چکیده انگلیسی

An oxygen separation tube with a composite structure in which a dense membrane is formed on a porous body was successfully fabricated using a newly developed mixed conducting oxide, SrCo0.9Nb0.1O3−δ (SCN). Using the tube obtained, it was confirmed that high-purity oxygen was separated from compressed air. The permeation rate reached 9 cm3 min− 1 cm- 2 at an oxygen collection rate of 20% under the condition of 900 °C and 10 atm air. It was also suggested that the oxygen separation rate followed the theoretical equation assuming a diffusion-limited process even in thin-membrane regions of, for example, 50 μm. From the measured permeation rate, oxide ionic conductivity was estimated to be around 100 S/m at 900 °C. Furthermore, stable oxygen separation from higher air pressure up to 20 atm was successfully observed, which proved the high stability of SCN as well as its superior permeability. The reliability of the fabricated separation tube was also confirmed through a long-term separation test over a half-year period conducted under 900 °C, 10 atm air.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 178, Issues 11–12, 15 May 2007, Pages 809–816
نویسندگان
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