کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1298687 | 974015 | 2008 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High temperature interface reactions of TiC, TiN, and SiC with palladium and rhodium
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Reactions of TiC, TiN, and SiC with palladium and rhodium at temperatures up to 1600 °C were examined using bulk diffusion couple experiments. Intermetallic phases at the ceramic–metal interfaces were observed using scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and transmission electron microscopy (TEM). The reactivity of the ceramics with these platinum group metals follows the order SiC ≫ TiC > TiN, and reactivity of the metals follows the order Pd > Rh. TiN–Pd interfaces were unique in that no intermetallic phase formation was observed at any of the annealing times and temperatures. The formation of distinct intermetallic phases at the SiC–Rh and TiC–Rh interfaces followed a non-parabolic behavior.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 179, Issue 39, 15 December 2008, Pages 2313–2321
Journal: Solid State Ionics - Volume 179, Issue 39, 15 December 2008, Pages 2313–2321
نویسندگان
Paul Demkowicz, Karen Wright, Jian Gan, David Petti,