کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1298687 974015 2008 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High temperature interface reactions of TiC, TiN, and SiC with palladium and rhodium
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
High temperature interface reactions of TiC, TiN, and SiC with palladium and rhodium
چکیده انگلیسی

Reactions of TiC, TiN, and SiC with palladium and rhodium at temperatures up to 1600 °C were examined using bulk diffusion couple experiments. Intermetallic phases at the ceramic–metal interfaces were observed using scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and transmission electron microscopy (TEM). The reactivity of the ceramics with these platinum group metals follows the order SiC ≫ TiC > TiN, and reactivity of the metals follows the order Pd > Rh. TiN–Pd interfaces were unique in that no intermetallic phase formation was observed at any of the annealing times and temperatures. The formation of distinct intermetallic phases at the SiC–Rh and TiC–Rh interfaces followed a non-parabolic behavior.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 179, Issue 39, 15 December 2008, Pages 2313–2321
نویسندگان
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