کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1298976 | 1498409 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and electrochemical behavior of tungsten oxide obtained by solid state reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Tungsten oxides have been used successfully as intercalation compounds of high performance batteries. In this communication we present a new and innovative route to obtain orthorhombic WO3 where the crystallographic structure can be carefully controlled. X-ray diffraction data indicates that a texture is obtained in the [0k0] direction, whereas XPS suggests that the valence of the tungsten atom is + 6. The electrochemical behavior of the oriented sample was studied by chronopotentiometry and its charge–discharge capacity was evaluated. The results showed stable values close to 100 mA h/g after the 70th cycle, which compares favorably to the best know WO3 compounds produced so far.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 7–8, 15 March 2006, Pages 697–701
Journal: Solid State Ionics - Volume 177, Issues 7–8, 15 March 2006, Pages 697–701
نویسندگان
E.A. Souza, A.O. Santos, R. Landers, F. Cunha, M.A. Macêdo,