کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299196 1498703 2016 16 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Coordination complexes of pnictogen(V) cations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Coordination complexes of pnictogen(V) cations
چکیده انگلیسی


• Pnictogen(V)-centred cationic systems behave as highly effective Lewis acceptor sites.
• Rare examples of these systems are reviewed.
• Synthesis, characterisation, structure and bonding are discussed.
• The compounds represent pnictogen analogues of transition metal coordination complexes.

The pnictogen elements can access a wide range of oxidation states and coordination numbers, but are usually associated with molecules that behave as Lewis bases. Some pnictogen based compounds exhibit Lewis acidic behaviour and the presence of a positive charge augments their electrophilicity. Pnictogen(V)-centred cationic systems have the potential to behave as highly effective Lewis acceptor sites, but are superficially developed. The rare examples of these systems are reviewed herein, including their synthesis, characterisation, structure and bonding. The molecules discussed are categorised by the generic formulae [PnX4L]+, [PnX4L2]+, [PnX2YL]+, [PnY2L2]+, [PnX3L]2+, [PnX3L2]2+ or [PnXYL2]2+, where X is a substituent such as halide or alkyl, Y is a divalent substituent such as O, S or NR, and L is a neutral ligand. The compounds represent pnictogen analogues of transition metal coordination complexes and identify a potentially broad new direction in coordination chemistry.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 324, 1 October 2016, Pages 1–16
نویسندگان
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