کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299222 1498778 2011 30 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Vanadium complexes immobilized on solid supports and their use as catalysts for oxidation and functionalization of alkanes and alkenes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Vanadium complexes immobilized on solid supports and their use as catalysts for oxidation and functionalization of alkanes and alkenes
چکیده انگلیسی

This review mainly discusses the immobilization strategies that have been used for vanadium complexes, typically mesoporous material, zeolites and polymers, the characterization procedures for the obtained materials, and their catalytic applications. The retention of the active metal compound within the catalyst may be based on (i) adsorption, (ii) the formation of covalent bonds between metal ligand and support, (iii) ion exchange, (iv) encapsulation, or (v) entrapment. The heterogenized complexes are used as catalysts for oxidations and functionalization of alkanes, alkenes and other substrates, and an account of the various applications reported is given.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 255, Issues 19–20, October 2011, Pages 2315–2344
نویسندگان
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