کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299389 1498807 2009 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases
چکیده انگلیسی

This review focuses on electron and proton transfers involving hexacarbonyl and substituted {2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe]H2ases), and on different mechanisms by which the synthetic models catalyze the reduction of protons. Selected aspects of the mechanisms proposed for the biological process on the basis of DFT calculations are also briefly presented.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 253, Issues 9–10, May 2009, Pages 1476–1494
نویسندگان
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