کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299408 1498810 2009 34 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism
چکیده انگلیسی

Coordination compounds based on the substituted o-iminoquinonato, o-iminosemiquinonato and o-amidophenolato ligands with transition metal ions are described from the viewpoint of their structural and magnetic properties. The present review summarizes data on homoleptic transition metal complexes of bulky bidentate N-aryl-o-iminoquinonato type ligands involving comparison with o-quinonato analogues; penta- and hexacoordinate bis-o-iminobenzoquinonato complexes of ML2X, ML2X2 and ML2L′ types; mono-o-iminobenzoquinonato complexes and complexes based on three-, tetra- and pentadentate bis-o-iminobenzoquinones. Synthetic aspects are also included.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 253, Issues 3–4, February 2009, Pages 291–324
نویسندگان
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