کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299485 1498821 2008 21 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Recent advances in copper-catalyzed oxidation of organic compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Recent advances in copper-catalyzed oxidation of organic compounds
چکیده انگلیسی

The copper-catalyzed oxidation of organic compounds has made considerable progress in the recent years. Molecular oxygen, aqueous hydrogen peroxide, tert-butyl hydroperoxide and peroxyesters have been employed as terminal oxidants for this purpose. The use of polymer and solid-supported catalysts, ionic liquids and fluorous biphase systems (FBS) has been demonstrated to facilitate the recyclability of the catalysts. Efforts have been made for the aqueous oxidation processes employing water-soluble copper complexes. Chiral catalysts have been designed and developed for the enantioselective oxidative coupling of 2-naphthols, Baeyer–Villiger oxidation and Kharasch–Sosnovsky reaction with high enantioselectivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 252, Issues 1–2, January 2008, Pages 134–154
نویسندگان
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