کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299485 | 1498821 | 2008 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Recent advances in copper-catalyzed oxidation of organic compounds
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
The copper-catalyzed oxidation of organic compounds has made considerable progress in the recent years. Molecular oxygen, aqueous hydrogen peroxide, tert-butyl hydroperoxide and peroxyesters have been employed as terminal oxidants for this purpose. The use of polymer and solid-supported catalysts, ionic liquids and fluorous biphase systems (FBS) has been demonstrated to facilitate the recyclability of the catalysts. Efforts have been made for the aqueous oxidation processes employing water-soluble copper complexes. Chiral catalysts have been designed and developed for the enantioselective oxidative coupling of 2-naphthols, Baeyer–Villiger oxidation and Kharasch–Sosnovsky reaction with high enantioselectivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 252, Issues 1–2, January 2008, Pages 134–154
Journal: Coordination Chemistry Reviews - Volume 252, Issues 1–2, January 2008, Pages 134–154
نویسندگان
T. Punniyamurthy, Laxmidhar Rout,