کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299490 | 1498821 | 2008 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Aspects of dihydrogen coordination chemistry relevant to reactivity in aqueous solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The aqueous coordination chemistry of dihydrogen has potential applications in inorganic biomimicry, chemoselective hydrogenation catalysis, and green chemistry. However, experimental and mechanistic studies that explore the aqueous behavior of these complexes are virtually unknown. This review identifies the motivation for studying aqueous dihydrogen coordination complexes by providing a summary of reactions that involve a dihydrogen ligand in highly polar solvents. The under-utilized potential of aqueous dihydrogen complexes in ionic hydrogenation reactions and in biomimicry is addressed. Finally, NMR methods for characterizing H–H bond distances in η2-H2 complexes are reviewed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 252, Issues 1–2, January 2008, Pages 212–230
Journal: Coordination Chemistry Reviews - Volume 252, Issues 1–2, January 2008, Pages 212–230
نویسندگان
Nathaniel K. Szymczak, David R. Tyler,