کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299591 | 1498758 | 2013 | 21 صفحه PDF | دانلود رایگان |
• We report the synthesis and application of metallacalixarenes.
• Metallacalixarenes possess magnetic and optical properties.
• Metallacalixarenes are promising cations, anions and neutral molecule receptors.
• Porous structures may adsorb N2 and/or H2and methanol/benzene vapors.
This review focuses on the synthesis and applications of organic–inorganic hybrid materials called metallacalixarenes. Two different subclasses of metallacalixarenes are presented: cyclic discrete oligomers based on heterocycles or nucleobases and metallacalixarenes as part of a polymeric network based on 1,3-dicarboxylate ligands. In addition to their potential application in gas adsorption/separations, magnetism and catalysis, metallacalixarenes might complex cations, anions, or neutral molecules due to their calixarene-like cavities.
Journal: Coordination Chemistry Reviews - Volume 257, Issues 15–16, August 2013, Pages 2192–2212