کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299637 1498762 2013 29 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxido-peroxido molybdenum(VI) complexes in catalytic and stoichiometric oxidations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Oxido-peroxido molybdenum(VI) complexes in catalytic and stoichiometric oxidations
چکیده انگلیسی

This review mainly discusses the application of oxido-peroxido Molybdenum(VI) complexes as catalysts or mediators in homogeneous or heterogeneous catalytic systems for oxidations of olefins, sulfides, alcohols, alkanes, and amines toward the synthesis of a variety of organic compounds, such as epoxides, sulfoxides, aldehydes and ketones, carboxylic acids, alcohols and nitroso compounds.

Figure optionsDownload high-quality image (87 K)Download as PowerPoint slideHighlights
► The catalytic activity of oxido-peroxido Mo(VI) complexes in oxidation reactions was explored.
► H2O2, urea hydrogen peroxide and tert-butyl hydroperoxide as oxidant.
► The catalytic results depend on complex structure and reaction conditions.
► The mechanisms suggested for the oxidation reactions were discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 257, Issues 7–8, April 2013, Pages 1093–1121
نویسندگان
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