کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299637 | 1498762 | 2013 | 29 صفحه PDF | دانلود رایگان |

This review mainly discusses the application of oxido-peroxido Molybdenum(VI) complexes as catalysts or mediators in homogeneous or heterogeneous catalytic systems for oxidations of olefins, sulfides, alcohols, alkanes, and amines toward the synthesis of a variety of organic compounds, such as epoxides, sulfoxides, aldehydes and ketones, carboxylic acids, alcohols and nitroso compounds.
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► The catalytic activity of oxido-peroxido Mo(VI) complexes in oxidation reactions was explored.
► H2O2, urea hydrogen peroxide and tert-butyl hydroperoxide as oxidant.
► The catalytic results depend on complex structure and reaction conditions.
► The mechanisms suggested for the oxidation reactions were discussed.
Journal: Coordination Chemistry Reviews - Volume 257, Issues 7–8, April 2013, Pages 1093–1121