کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1299928 1498735 2015 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches
ترجمه فارسی عنوان
سوئیچ های مولکولی مبتنی بر دیالایتی سلول های فوتو- و ردوکس-سوئیچینگ متمرکز بر فلز گذار
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• Cyclisisation/cycloreversion.
• Photoswitches metal carbonyls.
• Transition metal compounds.
• Photochemistry.
• Electrochemistry.

In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted.

In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed.Figure optionsDownload high-quality image (128 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volumes 282–283, 1 January 2015, Pages 77–86
نویسندگان
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