کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300000 | 1498753 | 2014 | 15 صفحه PDF | دانلود رایگان |
• We proposed a novel symbol approach for classification of molecular magnets.
• This approach provides a concise feature for labelling molecular magnets.
• The symbols can simplify the searching for certain molecular magnetism.
• We reviewed recent examples of magnetic metal-carboxylate coordination polymers.
• The construction of low-dimensional magnets has been focused.
The ever-growing family of molecule-based magnetic materials calls for a systematic classification of these structurally sophisticated and magnetically diverse compounds. Using magnetically active coordination polymers of metal carboxylates as representatives, we propose and illustrate in this review a symbol approach for their organization and categorization. By adopting this approach, the seemingly complex magneto-structural correlations in a wide variety of molecular magnetic materials, including single-molecule magnets, single-chain magnets, geometrically frustrated magnets, and high Curie-temperature magnets, can be readily discerned.
Journal: Coordination Chemistry Reviews - Volumes 258–259, January 2014, Pages 1–15