A symbol approach for classification of molecule-based magnetic materials exemplified by coordination polymers of metal carboxylates

• We proposed a novel symbol approach for classification of molecular magnets.
• This approach provides a concise feature for labelling molecular magnets.
• The symbols can simplify the searching for certain molecular magnetism.
• We reviewed recent examples of magnetic metal-carboxylate coordination polymers.
• The construction of low-dimensional magnets has been focused.

The ever-growing family of molecule-based magnetic materials calls for a systematic classification of these structurally sophisticated and magnetically diverse compounds. Using magnetically active coordination polymers of metal carboxylates as representatives, we propose and illustrate in this review a symbol approach for their organization and categorization. By adopting this approach, the seemingly complex magneto-structural correlations in a wide variety of molecular magnetic materials, including single-molecule magnets, single-chain magnets, geometrically frustrated magnets, and high Curie-temperature magnets, can be readily discerned.