کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300054 | 1498763 | 2013 | 22 صفحه PDF | دانلود رایگان |
This review describes recent advances in the synthesis, chemistry and applications of phosphine ligands containing one or more perfluoroalkyl, Rf, substituent. The methods reviewed are capable of generating a wide variety of monodentate, bidentate and PCP-pincer ligands containing Rf groups. Based on the chemistry of complexes containing these ligands, and compilations of their spectroscopic data and structural parameters it is shown that fluoroalkyl-containing phosphines have a distinct combination of steric and electronic properties, often quite different to fluoroaryl analogues. The catalytic activities displayed by complexes of these ligands are described.
► Comprehensive survey of monodenate, bidentate and pincer perfluoroalkyl-phosphines.
► A review of recently published methods of synthesizing Rf-containing phosphines.
► Summaries of structures and spectroscopic data available, upto 2011, for fluoroalkyl-phosphines.
► Applications in catalysis.
Journal: Coordination Chemistry Reviews - Volume 257, Issues 5–6, March 2013, Pages 880–901