کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300063 | 1498763 | 2013 | 18 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Phosphanides of calcium and their oxidation products
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
⺠Phosphanes are poor ligands for the rather hard calcium cations whereas calcium complexes with phosphane oxide ligands are feasible. ⺠Phosphanides and their oxidation products (phosphinites and phosphinates, and phosphonates) represent a multifaceted class of ligands in coordination chemistry. ⺠Phosphanides of calcium represent valuable catalysts for hydrophosphanylation reactions. ⺠Taking Grimm's hydride displacement law (O/NH/CH2 and O/Nâ/CHâ/C2â) into account, structures and properties of many compounds can be attributed to phosphorus-based acids and anions. ⺠Phosphorus-based anions with two or three oxygen atoms (phosphinates and phosphonates) always act as bridging ligands between calcium cations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 257, Issues 5â6, March 2013, Pages 1049-1066
Journal: Coordination Chemistry Reviews - Volume 257, Issues 5â6, March 2013, Pages 1049-1066
نویسندگان
Matthias Westerhausen, Sven Krieck, Jens Langer, Tareq M.A. Al-Shboul, Helmar Görls,