کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300184 974316 2005 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The magnetochemistry of verdazyl radical-based materials
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The magnetochemistry of verdazyl radical-based materials
چکیده انگلیسی

Stable organic radicals have received much attention as building blocks for the construction of molecular magnetic materials because they are readily functionalized using modern synthetic techniques. In this context, the nitroxide radical family has been the dominant class of radicals in molecular magnetochemistry. However, other stable radical systems have also been explored. One such example is the verdazyl family of radicals. Their high chemical stability and synthetic versatility make verdazyls one of the more attractive alternatives to nitroxides in molecular magnet design. This article reviews the magnetism of verdazyl-based systems, including through-bond coupling in polyradicals, coordination complexes and intermolecular interactions in the solid state.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 249, Issue 23, 1 December 2005, Pages 2612–2630
نویسندگان
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