کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300332 | 1498747 | 2014 | 41 صفحه PDF | دانلود رایگان |
• Complete overview of the wealth of actinide oxalate arrangements in the solid state.
• Important role of actinide oxalates particularly in the nuclear industry.
• Crystal growth methods adapted to actinide oxalates.
• Recent progress crystal growth and structure determination of transuranic oxalates.
• Ongoing research challenges with mixed actinide and/or mixed valence actinide oxalates.
Actinide oxalates are an important class of materials mainly for the nuclear industry. This review presents the crystal growth methods addressed to non-soluble actinide (III) and (IV) oxalates and to soluble actinyl oxalates. Actinide-oxalate discrete ions, one-dimensional coordination polymers and two- or three-dimensional frameworks are described for the different oxidation states of actinides in simple, double or triple actinide oxalates together with mixed actinide (IV)-lanthanide (III) or -actinide (III) and mixed ligands actinide oxalates. The main applications of actinide oxalates, particularly for radioactive waste management and nuclear fuel treatment and recycling are also reported.
Figure optionsDownload high-quality image (138 K)Download as PowerPoint slide
Journal: Coordination Chemistry Reviews - Volumes 266–267, May 2014, Pages 28–68