کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300389 | 1498761 | 2013 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Mixed valency of a 5d element: The osmium example Mixed valency of a 5d element: The osmium example](/preview/png/1300389.png)
Pronounced spin–orbit coupling effects and the stabilization of higher oxidation states for the osmium analogues of mixed-valent ruthenium compounds result in more complex electronic spectra, frequent EPR silence, and valence transfer-dependent comproportionation constants for the intermediates.
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► Relative to ruthenium mixed-valent systems, the osmium analogues exhibit different donor/acceptor characteristics.
► Comproportionation constants reflect the ligand-dependent hole- vs. electron-transfer mechanism of valence exchange.
► Strong spin–orbit coupling results in frequent EPR silence due to rapid relaxation and line broadening.
► Several low-energy absorption bands are usually observed because of strong spin–orbit coupling effects.
Journal: Coordination Chemistry Reviews - Volume 257, Issues 9–10, May 2013, Pages 1650–1659