کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300537 | 1498839 | 2006 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photochemical reactions of Group 6 metal carbonyls with alkenes
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Photochemical reactions of Group 6 metal carbonyls with alkenes Photochemical reactions of Group 6 metal carbonyls with alkenes](/preview/png/1300537.png)
چکیده انگلیسی
The aim of this survey article is to bring into focus intriguing areas of Group 6 metal alkene coordination chemistry that have not been extensively surveyed to date. Photochemical reactions of Group 6 transition metal carbonyls with alkenes and the formation of alkene carbonyl complexes of the type: [M(CO)5(η2-alkene)], [M(CO)4(η2-alkene)2], and [M(CO)3(η2-alkene)3] are the point of departure. The crystal structures of these compounds together with their spectroscopic characteristics in solution are discussed. An overview of the reactivity and catalytic activity of these compounds is also given. Special attention is given to catalytic reactions that lead to the formation of new carbon-carbon bonds, such as metathesis, ring-opening metathesis polymerization of cyclic olefins (ROMP), and the addition of haloalkanes to the double bond of olefin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 250, Issues 9â10, May 2006, Pages 976-990
Journal: Coordination Chemistry Reviews - Volume 250, Issues 9â10, May 2006, Pages 976-990
نویسندگان
Teresa SzymaÅska-Buzar,