کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1300742 | 1498838 | 2006 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Design, synthesis, characterization and utilization of hydrogen bonded networks based on functionalized organometallic sandwich compounds and the occurrence of crystal polymorphism
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
The design and construction of hybrid organic–organometallic and inorganic–organometallic crystalline materials formed by hydrogen bonded functionalized organometallic sandwich compounds are described. It is shown that the ionic or neutral nature of the building blocks can be exploited to control the strength of intermolecular bonding and the structure–function relationship. The occurrence of crystal polymorphism associated with hydrogen bonded dimers and hydrogen bonded networks is discussed. It is also argued that solid–solid and solid–gas reactions involving preformed hydrogen bonded organometallic molecular crystals provide a viable “green” route to the preparation of novel hybrid molecular crystalline materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 250, Issues 11–12, June 2006, Pages 1267–1285
Journal: Coordination Chemistry Reviews - Volume 250, Issues 11–12, June 2006, Pages 1267–1285
نویسندگان
Dario Braga, Stefano L. Giaffreda, Fabrizia Grepioni, Lucia Maini, Marco Polito,