کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300742 1498838 2006 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Design, synthesis, characterization and utilization of hydrogen bonded networks based on functionalized organometallic sandwich compounds and the occurrence of crystal polymorphism
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Design, synthesis, characterization and utilization of hydrogen bonded networks based on functionalized organometallic sandwich compounds and the occurrence of crystal polymorphism
چکیده انگلیسی

The design and construction of hybrid organic–organometallic and inorganic–organometallic crystalline materials formed by hydrogen bonded functionalized organometallic sandwich compounds are described. It is shown that the ionic or neutral nature of the building blocks can be exploited to control the strength of intermolecular bonding and the structure–function relationship. The occurrence of crystal polymorphism associated with hydrogen bonded dimers and hydrogen bonded networks is discussed. It is also argued that solid–solid and solid–gas reactions involving preformed hydrogen bonded organometallic molecular crystals provide a viable “green” route to the preparation of novel hybrid molecular crystalline materials.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 250, Issues 11–12, June 2006, Pages 1267–1285
نویسندگان
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