کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300877 974464 2016 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The electronic structure and photochemistry of transition metal thionitrosyl complexes
ترجمه فارسی عنوان
ساختار الکترونیک و فوتوشیمی از ترکیبات تیتونیتروسیل فلز گذرا
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• The NS ligand is a weaker π acceptor than the NO ligand.
• NS can be photoreleased from thionitrosyl complexes.
• The reactivity of NS in solution is similar to NO.

A review of the electronic structure of transition metal thionitrosyl complexes is given. The optical spectra and EPR spectra of the complexes are discussed along with the results of theoretical calculations of the electronic structure including geometry optimizations. The σ donor and π donor/acceptor properties of the NS ligand are compared with the isovalent NO ligand. The photochemistry of thionitrosyl complexes is presented. The reactivity of the photoreleased NS radical in solution is discussed.

Figure optionsDownload high-quality image (93 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 306, Part 2, 1 January 2016, Pages 544–557
نویسندگان
,