کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300892 1498718 2015 17 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts
چکیده انگلیسی


• New hydrogen evolving molecular cobalt–polypyridyl catalysts have recently emerged.
• Their evaluation for electro- and photocatalytic hydrogen production is discussed.
• These robust catalysts display high activities under fully aqueous conditions.
• Mechanistic considerations and structure–activity relationships are highlighted.

The search for efficient noble metal-free hydrogen-evolving catalysts is the subject of intense research activity. A new family of molecular cobalt(II)–polypyridyl catalysts has recently emerged. These catalysts prove more robust under reductive conditions than other cobalt-based systems and display high activities under fully aqueous conditions. This review discusses the design, characterization, and evaluation of these catalysts for electrocatalytic and light-driven hydrogen production. Mechanistic considerations are addressed and structure–catalytic activity relationships identified in order to guide the future design of more efficient catalytic systems.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volumes 304–305, 1 December 2015, Pages 3–19
نویسندگان
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